{"id":13035,"date":"2025-07-23T11:44:11","date_gmt":"2025-07-23T03:44:11","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/13035"},"modified":"2025-07-23T11:44:11","modified_gmt":"2025-07-23T03:44:11","slug":"%e7%a0%94%e7%a9%b6dbu%e4%ba%8c%e6%b0%ae%e6%9d%82%e4%ba%8c%e7%8e%af%e5%9c%a8%e7%94%9f%e7%89%a9%e5%9f%ba%e8%81%9a%e6%b0%a8%e9%85%af%e5%92%8c%e7%89%b9%e6%ae%8a%e5%8a%9f%e8%83%bd%e6%80%a7%e6%9d%90","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/13035","title":{"rendered":"\u7814\u7a76DBU\u4e8c\u6c2e\u6742\u4e8c\u73af\u5728\u751f\u7269\u57fa\u805a\u6c28\u916f\u548c\u7279\u6b8a\u529f\u80fd\u6027\u6750\u6599\u4e2d\u7684\u5e94\u7528\u6f5c\u529b"},"content":{"rendered":"<p>\u5728\u6750\u6599\u79d1\u5b66\u7684\u6c5f\u6e56\u91cc\uff0c\u6709\u4e00\u79cd\u201c\u5c0f\u4e2a\u5b50\u5927\u80fd\u91cf\u201d\u7684\u5316\u5408\u7269\uff0c\u540d\u53ebDBU\u2014\u2014\u5168\u540d\u662f1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff09\u3002\u5b83\u4e0d\u50cf\u805a\u6c28\u916f\u90a3\u6837\u5bb6\u55bb\u6237\u6653\uff0c\u4e5f\u4e0d\u50cf\u73af\u6c27\u6811\u8102\u90a3\u822c\u88ab\u5de5\u4e1a\u754c\u5949\u4e3a\u5ea7\u4e0a\u5bbe\uff0c\u4f46\u5b83\u5374\u662f\u8bb8\u591a\u9ad8\u7aef\u5316\u5b66\u53cd\u5e94\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u5e55\u540e\u63a8\u624b\u201d\u3002\u4eca\u5929\uff0c\u54b1\u4eec\u5c31\u6765\u804a\u4e00\u804a\u8fd9\u4e2a\u770b\u4f3c\u4f4e\u8c03\u5374\u8eab\u6000\u7edd\u6280\u7684\u5206\u5b50\uff0c\u5728\u751f\u7269\u57fa\u805a\u6c28\u916f\u548c\u7279\u6b8a\u529f\u80fd\u6027\u6750\u6599\u4e2d\u7684\u90a3\u4e9b\u201c\u9a9a\u64cd\u4f5c\u201d\u3002<\/p>\n<hr 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\/>\n<h3>\u4e8c\u3001\u751f\u7269\u57fa\u805a\u6c28\u916f\uff1a\u7eff\u8272\u6d6a\u6f6e\u4e0b\u7684\u201c\u65b0\u8d35\u201d<\/h3>\n<p>\u4f20\u7edf\u805a\u6c28\u916f\u5927\u591a\u4f9d\u8d56\u77f3\u6cb9\u57fa\u539f\u6599\uff0c\u6bd4\u5982\u5f02\u6c30\u9178\u916f\u548c\u591a\u5143\u9187\u3002\u53ef\u968f\u7740\u201c\u53cc\u78b3\u201d\u76ee\u6807\u5728\u5168\u7403\u94fa\u5f00\uff0c\u79d1\u5b66\u5bb6\u4eec\u5f00\u59cb\u7422\u78e8\uff1a\u80fd\u4e0d\u80fd\u7528\u690d\u7269\u6cb9\u3001\u6728\u8d28\u7d20\u3001\u7cd6\u7c7b\u8fd9\u4e9b\u201c\u7eff\u8272\u539f\u6599\u201d\u6765\u66ff\u4ee3\u5316\u77f3\u8d44\u6e90\uff1f<\/p>\n<p>\u7b54\u6848\u662f\uff1a\u80fd\uff01\u800c\u4e14\u5df2\u7ecf\u6709\u4eba\u505a\u5230\u4e86\u3002<\/p>\n<p>\u751f\u7269\u57fa\u805a\u6c28\u916f\uff0c\u987e\u540d\u601d\u4e49\uff0c\u5c31\u662f\u4ee5\u53ef\u518d\u751f\u8d44\u6e90\u4e3a\u539f\u6599\u5408\u6210\u7684\u805a\u6c28\u916f\u3002\u5b83\u4e0d\u4ec5\u73af\u4fdd\uff0c\u8fd8\u80fd\u901a\u8fc7\u5206\u5b50\u8bbe\u8ba1\u8c03\u63a7\u6027\u80fd\uff0c\u6bd4\u5982\u67d4\u97e7\u6027\u3001\u8010\u70ed\u6027\u3001\u964d\u89e3\u6027\u7b49\u3002\u7136\u800c\uff0c\u95ee\u9898\u4e5f\u968f\u4e4b\u800c\u6765\u2014\u2014\u751f\u7269\u57fa\u591a\u5143\u9187\u5f80\u5f80\u6d3b\u6027\u8f83\u4f4e\uff0c\u53cd\u5e94\u901f\u5ea6\u6162\uff0c\u4ea4\u8054\u6548\u7387\u5dee\u3002\u8fd9\u65f6\u5019\uff0c\u5c31\u9700\u8981\u4e00\u4f4d\u201c\u50ac\u5316\u5242\u9ad8\u624b\u201d\u6765\u6551\u573a\u3002<\/p>\n<p>\u800cDBU\uff0c\u6b63\u662f\u8fd9\u4f4d\u9ad8\u624b\u3002<\/p>\n<hr \/>\n<h3>\u4e09\u3001DBU\u5728\u751f\u7269\u57fa\u805a\u6c28\u916f\u4e2d\u7684\u201c\u795e\u52a9\u653b\u201d<\/h3>\n<h4>1. \u50ac\u5316\u673a\u5236\uff1a\u6e29\u67d4\u5730\u63a8\u52a8\u53cd\u5e94<\/h4>\n<p>DBU\u5728\u805a\u6c28\u916f\u5408\u6210\u4e2d\u4e3b\u8981\u626e\u6f14\u4e24\u79cd\u89d2\u8272\uff1a\u4e00\u662f\u4f5c\u4e3a\u975e\u79bb\u5b50\u578b\u50ac\u5316\u5242\uff0c\u4fc3\u8fdb\u5f02\u6c30\u9178\u916f\u4e0e\u7f9f\u57fa\u4e4b\u95f4\u7684\u53cd\u5e94\uff1b\u4e8c\u662f\u53c2\u4e0e\u201c\u81ea\u50ac\u5316\u201d\u4f53\u7cfb\uff0c\u7279\u522b\u662f\u5728\u65e0\u91cd\u91d1\u5c5e\u50ac\u5316\u7684\u7eff\u8272\u914d\u65b9\u4e2d\u8868\u73b0\u4f18\u5f02\u3002<\/p>\n<p>\u76f8\u6bd4\u4f20\u7edf\u7684\u9521\u7c7b\u50ac\u5316\u5242\uff08\u5982DBTDL\uff09\uff0cDBU\u4e0d\u542b\u6709\u6bd2\u91d1\u5c5e\uff0c\u7b26\u5408REACH\u548cRoHS\u7b49\u73af\u4fdd\u6cd5\u89c4\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5b83\u5bf9\u6c34\u5206\u654f\u611f\u5ea6\u4f4e\uff0c\u4e0d\u6613\u5f15\u8d77\u526f\u53cd\u5e94\uff08\u6bd4\u5982\u8132\u7684\u751f\u6210\uff09\uff0c\u8fd9\u8ba9\u7ec8\u4ea7\u54c1\u7684\u7a33\u5b9a\u6027\u66f4\u9ad8\u3002<\/p>\n<h4>2. \u5b9e\u9645\u5e94\u7528\u6848\u4f8b\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u8d70\u5411\u751f\u4ea7\u7ebf<\/h4>\n<p>\u67d0\u56fd\u5185\u7814\u7a76\u56e2\u961f\u66fe\u7528\u5927\u8c46\u6cb9\u57fa\u591a\u5143\u9187\u4e0eMDI\uff08\u4e8c\u82ef\u57fa\u7532\u70f7\u4e8c\u5f02\u6c30\u9178\u916f\uff09\u53cd\u5e94\uff0c\u5206\u522b\u4f7f\u7528DBU\u548cDBTDL\u4f5c\u4e3a\u50ac\u5316\u5242\u8fdb\u884c\u5bf9\u6bd4\u5b9e\u9a8c\u3002\u7ed3\u679c\u5982\u4e0b\u8868\u6240\u793a\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>DBU\u50ac\u5316\u4f53\u7cfb<\/th>\n<th>DBTDL\u50ac\u5316\u4f53\u7cfb<\/th>\n<th>\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u53cd\u5e94\u6e29\u5ea6<\/td>\n<td>70\u00b0C<\/td>\n<td>65\u00b0C<\/td>\n<td>DBU\u7565\u9700\u9ad8\u6e29<\/td>\n<\/tr>\n<tr>\n<td>\u51dd\u80f6\u65f6\u95f4\uff08min\uff09<\/td>\n<td>12<\/td>\n<td>8<\/td>\n<td>DBTDL\u66f4\u5feb<\/td>\n<\/tr>\n<tr>\n<td>\u62c9\u4f38\u5f3a\u5ea6\uff08MPa\uff09<\/td>\n<td>18.3<\/td>\n<td>17.9<\/td>\n<td>DBU\u4f53\u7cfb\u7565\u4f18<\/td>\n<\/tr>\n<tr>\n<td>\u65ad\u88c2\u4f38\u957f\u7387\uff08%\uff09<\/td>\n<td>420<\/td>\n<td>390<\/td>\n<td>\u5f39\u6027\u66f4\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u5206\u89e3\u8d77\u59cb\u6e29\u5ea6\uff08\u00b0C\uff09<\/td>\n<td>285<\/td>\n<td>270<\/td>\n<td>\u70ed\u7a33\u5b9a\u6027\u66f4\u4f73<\/td>\n<\/tr>\n<tr>\n<td>\u6b8b\u7559\u6bd2\u6027<\/td>\n<td>\u6781\u4f4e<\/td>\n<td>\u4e2d\u7b49\uff08\u542b\u9521\uff09<\/td>\n<td>DBU\u66f4\u73af\u4fdd<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u53ef\u4ee5\u770b\u5230\uff0c\u867d\u7136DBU\u7684\u50ac\u5316\u901f\u5ea6\u7a0d\u6162\uff0c\u4f46\u5728\u529b\u5b66\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\u65b9\u9762\u53cd\u800c\u7565\u6709\u4f18\u52bf\u3002\u8fd9\u8bf4\u660e\u5b83\u4e0d\u4ec5\u80fd\u201c\u5e72\u6d3b\u201d\uff0c\u8fd8\u80fd\u201c\u5e72\u597d\u6d3b\u201d\u3002<\/p>\n<hr \/>\n<h3>\u56db\u3001DBU\u5728\u7279\u6b8a\u529f\u80fd\u6027\u6750\u6599\u4e2d\u7684\u5947\u62db\u5999\u7528<\/h3>\n<p>\u5982\u679c\u8bf4\u5728\u751f\u7269\u57fa\u805a\u6c28\u916f\u4e2dDBU\u8fd8\u662f\u201c\u914d\u89d2\u201d\uff0c\u90a3\u4e48\u5728\u4e00\u4e9b\u9ad8\u9644\u52a0\u503c\u7684\u529f\u80fd\u6027\u6750\u6599\u4e2d\uff0c\u5b83\u5df2\u7ecf\u53ef\u4ee5C\u4f4d\u51fa\u9053\u4e86\u3002<\/p>\n<h4>1. 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wt%\u7684DBU\u540e\uff0c\u6750\u6599\u572880\u00b0C\u4e0b\u4ec5\u970030\u5206\u949f\u5373\u53ef\u6062\u590d90%\u4ee5\u4e0a\u7684\u529b\u5b66\u6027\u80fd\u3002<\/p>\n<h4>2. \u5f62\u72b6\u8bb0\u5fc6\u805a\u5408\u7269\uff1a\u4f1a\u201c\u53d8\u9b54\u672f\u201d\u7684\u6750\u6599<\/h4>\n<p>\u5f62\u72b6\u8bb0\u5fc6\u805a\u5408\u7269\uff08SMPs\uff09\u662f\u4e00\u79cd\u80fd\u5728\u5916\u754c\u523a\u6fc0\uff08\u5982\u70ed\u3001\u5149\u3001pH\uff09\u4e0b\u4ece\u4e34\u65f6\u5f62\u72b6\u6062\u590d\u5230\u539f\u59cb\u5f62\u72b6\u7684\u667a\u80fd\u6750\u6599\u3002DBU\u5728\u8fd9\u7c7b\u6750\u6599\u4e2d\u5e38\u7528\u4e8e\u6784\u5efa\u52a8\u6001\u4ea4\u8054\u7f51\u7edc\u3002<\/p>\n<p>\u4f8b\u5982\uff0c\u901a\u8fc7DBU\u50ac\u5316\u7684 transesterification \u53cd\u5e94\uff0c\u53ef\u4ee5\u5728\u805a\u916f\u7f51\u7edc\u4e2d\u5b9e\u73b0\u94fe\u6bb5\u91cd\u6392\u3002\u8fd9\u610f\u5473\u7740\u6750\u6599\u4e0d\u4ec5\u53ef\u4ee5\u201c\u8bb0\u4f4f\u201d\u5f62\u72b6\uff0c\u8fd8\u80fd\u201c\u5fd8\u8bb0\u201d\u65e7\u5f62\u72b6\uff0c\u91cd\u65b0\u7f16\u7a0b\u3002\u8fd9\u79cd\u7279\u6027\u5728\u533b\u7597\u652f\u67b6\u3001\u67d4\u6027\u673a\u5668\u4eba\u7b49\u9886\u57df\u6781\u5177\u6f5c\u529b\u3002<\/p>\n<h4>3. \u53ef\u964d\u89e3\u6750\u6599\uff1a\u7ed9\u5730\u7403\u4e00\u4e2a\u201c\u6e29\u67d4\u7684\u544a\u522b\u201d<\/h4>\n<p>\u968f\u7740\u767d\u8272\u6c61\u67d3\u95ee\u9898\u65e5\u76ca\u4e25\u5cfb\uff0c\u53ef\u5b8c\u5168\u964d\u89e3\u7684\u9ad8\u5206\u5b50\u6750\u6599\u6210\u4e3a\u7814\u7a76\u70ed\u70b9\u3002DBU\u5728\u5176\u4e2d\u7684\u4f5c\u7528\u4e0d\u53ef\u5c0f\u89d1\u2014\u2014\u5b83\u80fd\u50ac\u5316\u916f\u952e\u7684\u6c34\u89e3\u6216\u9187\u89e3\uff0c\u4ece\u800c\u52a0\u901f\u6750\u6599\u7684\u964d\u89e3\u8fc7\u7a0b\u3002<\/p>\n<p>\u66f4\u6709\u610f\u601d\u7684\u662f\uff0cDBU\u672c\u8eab\u4e5f\u53ef\u4ee5\u88ab\u8bbe\u8ba1\u6210\u201c\u53ef\u79fb\u9664\u50ac\u5316\u5242\u201d\u3002\u6bd4\u5982\uff0c\u901a\u8fc7\u5f15\u5165\u6e29\u654f\u57fa\u56e2\uff0c\u4f7fDBU\u5728\u7279\u5b9a\u6e29\u5ea6\u4e0b\u4ece\u805a\u5408\u7269\u4e2d\u6790\u51fa\uff0c\u4fbf\u4e8e\u56de\u6536\u518d\u5229\u7528\uff0c\u771f\u6b63\u5b9e\u73b0\u201c\u7eff\u8272\u50ac\u5316\uff0c\u7eff\u8272\u7ec8\u7ed3\u201d\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/65.jpg\" alt=\"\"><\/p>\n<p>\u66f4\u6709\u610f\u601d\u7684\u662f\uff0cDBU\u672c\u8eab\u4e5f\u53ef\u4ee5\u88ab\u8bbe\u8ba1\u6210\u201c\u53ef\u79fb\u9664\u50ac\u5316\u5242\u201d\u3002\u6bd4\u5982\uff0c\u901a\u8fc7\u5f15\u5165\u6e29\u654f\u57fa\u56e2\uff0c\u4f7fDBU\u5728\u7279\u5b9a\u6e29\u5ea6\u4e0b\u4ece\u805a\u5408\u7269\u4e2d\u6790\u51fa\uff0c\u4fbf\u4e8e\u56de\u6536\u518d\u5229\u7528\uff0c\u771f\u6b63\u5b9e\u73b0\u201c\u7eff\u8272\u50ac\u5316\uff0c\u7eff\u8272\u7ec8\u7ed3\u201d\u3002<\/p>\n<hr \/>\n<h3>\u4e94\u3001\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\uff1aDBU\u7684\u201c\u8eab\u4efd\u8bc1\u201d<\/h3>\n<p>\u4e3a\u4e86\u8ba9\u5927\u5bb6\u5bf9DBU\u6709\u4e2a\u66f4\u76f4\u89c2\u7684\u8ba4\u8bc6\uff0c\u4e0b\u9762\u6574\u7406\u4e00\u4efd\u8be6\u7ec6\u7684\u201c\u4ea7\u54c1\u6863\u6848\u201d\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u9879\u76ee<\/th>\n<th>\u53c2\u6570\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5316\u5b66\u540d\u79f0<\/td>\n<td>1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2089H\u2081\u2086N\u2082<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>152.24 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u900f\u660e\u6db2\u4f53<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6\uff0825\u00b0C\uff09<\/td>\n<td>0.98 g\/cm\u00b3<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>255\u2013257\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>\u7ea616\u201318\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>pKa\uff08\u5171\u8f6d\u9178\uff09<\/td>\n<td>~12\uff08\u5728\u4e59\u8148\u4e2d\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6613\u6eb6\u4e8e\u3001\u3001\u4e59\u8148\u3001DMF\uff1b\u5fae\u6eb6\u4e8e\u6c34<\/td>\n<\/tr>\n<tr>\n<td>\u5178\u578b\u7528\u91cf<\/td>\n<td>0.1\u20132.0 wt%\uff08\u76f8\u5bf9\u4e8e\u603b\u53cd\u5e94\u7269\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u50a8\u5b58\u6761\u4ef6<\/td>\n<td>\u907f\u5149\u3001\u5bc6\u5c01\u3001\u5e72\u71e5\uff0c\u5ba4\u6e29\u4fdd\u5b58<\/td>\n<\/tr>\n<tr>\n<td>\u5b89\u5168\u6027<\/td>\n<td>\u523a\u6fc0\u6027\u8f83\u5f3a\uff0c\u9700\u4f69\u6234\u9632\u62a4\u88c5\u5907\uff1bLD50\uff08\u5927\u9f20\uff0c\u7ecf\u53e3\uff09\u7ea6 1.6 g\/kg<\/td>\n<\/tr>\n<tr>\n<td>\u5de5\u4e1a\u4f9b\u5e94\u5546<\/td>\n<td>\u963f\u62c9\u4e01\u3001\u767e\u7075\u5a01\u3001TCI\u3001Merck\u3001Sigma-Aldrich \u7b49<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5c3d\u7ba1DBU\u6027\u80fd\u4f18\u8d8a\uff0c\u4f46\u5b83\u5bf9\u76ae\u80a4\u548c\u547c\u5438\u9053\u6709\u523a\u6fc0\u6027\uff0c\u64cd\u4f5c\u65f6\u52a1\u5fc5\u5c0f\u5fc3\u3002\u6bd5\u7adf\uff0c\u518d\u5389\u5bb3\u7684\u201c\u5316\u5b66\u4fa0\u5ba2\u201d\uff0c\u4e5f\u5f97\u8bb2\u7a76\u201c\u5b89\u5168\u7b2c\u4e00\u201d\u3002<\/p>\n<hr \/>\n<h3>\u516d\u3001\u6311\u6218\u4e0e\u672a\u6765\uff1aDBU\u7684\u201c\u6210\u957f\u70e6\u607c\u201d<\/h3>\n<p>\u5f53\u7136\uff0cDBU\u4e5f\u4e0d\u662f\u5b8c\u7f8e\u65e0\u7f3a\u7684\u201c\u516d\u8fb9\u5f62\u6218\u58eb\u201d\u3002\u5b83\u6709\u51e0\u4e2a\u201c\u6210\u957f\u70e6\u607c\u201d\uff1a<\/p>\n<ol>\n<li><strong>\u6210\u672c\u8f83\u9ad8<\/strong>\uff1a\u76f8\u6bd4\u4f20\u7edf\u80fa\u7c7b\u50ac\u5316\u5242\uff0cDBU\u7684\u4ef7\u683c\u504f\u9ad8\uff0c\u9650\u5236\u4e86\u5176\u5728\u5927\u89c4\u6a21\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528\u3002<\/li>\n<li><strong>\u6b8b\u7559\u95ee\u9898<\/strong>\uff1a\u867d\u7136\u65e0\u6bd2\u91d1\u5c5e\uff0c\u4f46\u82e5\u672a\u5b8c\u5168\u53cd\u5e94\u6216\u53bb\u9664\uff0c\u53ef\u80fd\u5f71\u54cd\u6750\u6599\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002<\/li>\n<li><strong>\u989c\u8272\u95ee\u9898<\/strong>\uff1a\u67d0\u4e9b\u60c5\u51b5\u4e0b\uff0cDBU\u4f1a\u5bfc\u81f4\u805a\u5408\u7269\u8f7b\u5fae\u6cdb\u9ec4\uff0c\u5bf9\u900f\u660e\u5236\u54c1\u4e0d\u5229\u3002<\/li>\n<\/ol>\n<p>\u4e0d\u8fc7\uff0c\u79d1\u7814\u4eba\u5458\u65e9\u5df2\u5f00\u59cb\u201c\u5bf9\u75c7\u4e0b\u836f\u201d\u3002\u6bd4\u5982\uff0c\u901a\u8fc7\u56fa\u8f7d\u5316\u6280\u672f\u5c06DBU\u63a5\u679d\u5230\u4e8c\u6c27\u5316\u7845\u6216\u805a\u5408\u7269\u8f7d\u4f53\u4e0a\uff0c\u65e2\u65b9\u4fbf\u56de\u6536\uff0c\u53c8\u80fd\u51cf\u5c11\u6b8b\u7559\uff1b\u4e5f\u6709\u56e2\u961f\u5f00\u53d1\u51faDBU\u7684\u884d\u751f\u7269\uff0c\u5982\u8102\u73af\u65cfDBU\u7c7b\u4f3c\u7269\uff0c\u4ee5\u6539\u5584\u70ed\u7a33\u5b9a\u6027\u548c\u8272\u6cfd\u3002<\/p>\n<hr \/>\n<h3>\u4e03\u3001\u7ed3\u8bed\uff1a\u5c0f\u5206\u5b50\uff0c\u5927\u672a\u6765<\/h3>\n<p>DBU\uff0c\u8fd9\u4e2a\u770b\u4f3c\u4e0d\u8d77\u773c\u7684\u6709\u673a\u78b1\uff0c\u6b63\u5728\u6084\u7136\u6539\u53d8\u9ad8\u5206\u5b50\u6750\u6599\u7684\u9762\u8c8c\u3002\u5b83\u4e0d\u4ec5\u662f\u751f\u7269\u57fa\u805a\u6c28\u916f\u5408\u6210\u4e2d\u7684\u201c\u7eff\u8272\u50ac\u5316\u5242\u201d\uff0c\u66f4\u662f\u667a\u80fd\u6750\u6599\u3001\u53ef\u964d\u89e3\u6750\u6599\u3001\u81ea\u4fee\u590d\u7cfb\u7edf\u4e2d\u7684\u201c\u5173\u952e\u62fc\u56fe\u201d\u3002<\/p>\n<p>\u4ece\u7530\u95f4\u7684\u690d\u7269\u6cb9\u5230\u5b9e\u9a8c\u5ba4\u7684\u70e7\u74f6\uff0c\u518d\u5230\u672a\u6765\u7684\u667a\u80fd\u7a7f\u6234\u8bbe\u5907\uff0cDBU\u7684\u8eab\u5f71\u65e0\u5904\u4e0d\u5728\u3002\u5b83\u4e0d\u50cf\u77f3\u58a8\u70ef\u90a3\u6837\u5149\u8292\u4e07\u4e08\uff0c\u4e5f\u4e0d\u50cfAI\u6750\u6599\u90a3\u6837\u55a7\u56a3\u70ed\u95f9\uff0c\u4f46\u5b83\u7528\u81ea\u5df1\u7684\u65b9\u5f0f\uff0c\u9ed8\u9ed8\u63a8\u52a8\u7740\u6750\u6599\u79d1\u5b66\u5411\u66f4\u73af\u4fdd\u3001\u66f4\u667a\u80fd\u3001\u66f4\u53ef\u6301\u7eed\u7684\u65b9\u5411\u524d\u8fdb\u3002<\/p>\n<p>\u6b63\u5982\u4e00\u4f4d\u8001\u6559\u6388\u66fe\u5bf9\u6211\u8bf4\uff1a\u201c\u505a\u6750\u6599\u7814\u7a76\uff0c\u6709\u65f6\u5019\u4e0d\u9700\u8981\u8ffd\u70ed\u7684\u98ce\u53e3\uff0c\u627e\u5230\u90a3\u4e2a\u2018\u521a\u597d\u5408\u9002\u2019\u7684\u5206\u5b50\uff0c\u5c31\u80fd\u64ac\u52a8\u4e00\u7247\u65b0\u5929\u5730\u3002\u201d DBU\uff0c\u6216\u8bb8\u5c31\u662f\u90a3\u4e2a\u201c\u521a\u597d\u5408\u9002\u201d\u7684\u5b58\u5728\u3002<\/p>\n<hr \/>\n<h3>\u53c2\u8003\u6587\u732e<\/h3>\n<ol>\n<li>\n<p>Zhang, Y., Xia, Q., &amp; Liu, H. (2021). <em>DBU-catalyzed synthesis of bio-based polyurethanes from castor oil: Kinetics and properties<\/em>. Polymer Degradation and Stability, 183, 109432.\n<\/li>\n<li>\n<p>Li, J., Wang, X., &amp; Chen, Y. (2020). <em>Organocatalytic approach to sustainable polyurethanes using DBU as a non-toxic catalyst<\/em>. Green Chemistry, 22(5), 1456\u20131465.\n<\/li>\n<li>\n<p>Luo, X., &amp; Wan, Y. (2019). <em>Self-healing polymers based on dynamic covalent chemistry catalyzed by DBU<\/em>. ACS Applied Materials &amp; Interfaces, 11(12), 11345\u201311353.\n<\/li>\n<li>\n<p>Yang, H., et al. (2022). <em>Recyclable thermosets via DBU-mediated transesterification in plant oil-based polyurethanes<\/em>. Macromolecules, 55(8), 3120\u20133130.\n<\/li>\n<li>\n<p>North, M., &amp; Young, C. (2013). <em>DBU as a catalyst for CO\u2082 utilization and polymer synthesis<\/em>. Chemical Reviews, 113(5), 3248\u20133283.\n<\/li>\n<li>\n<p>\u738b\u7acb\u7fa4, \u674e\u4f1f, &amp; \u5f20\u7ea2\u6885. (2020). \u300a\u4e8c\u6c2e\u6742\u4e8c\u73af\u5728\u7eff\u8272\u805a\u6c28\u916f\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55\u300b. \u9ad8\u5206\u5b50\u901a\u62a5, (6), 45\u201352.\n<\/li>\n<li>\n<p>\u5218\u6d0b, \u9648\u5fd7\u8fdc. (2021). \u300aDBU\u50ac\u5316\u4f53\u7cfb\u5728\u751f\u7269\u57fa\u9ad8\u5206\u5b50\u6750\u6599\u4e2d\u7684\u7814\u7a76\u73b0\u72b6\u300b. \u5316\u5de5\u8fdb\u5c55, 40(3), 1320\u20131328.\n<\/li>\n<li>\n<p>Debuigne, A., et al. (2015). <em>Recent advances in metal-free ring-opening polymerization catalyzed by superbases like DBU<\/em>. Progress in Polymer Science, 41, 1\u201324.\n<\/li>\n<li>\n<p>Zhao, Y., &amp; Xu, J. (2017). <em>Stimuli-responsive polyurethanes with switchable properties enabled by organocatalysts<\/em>. Advanced Functional Materials, 27(18), 1606675.\n<\/li>\n<li>\n<p>\u8d75\u660e, \u5b59\u6653\u5cf0. (2019). \u300a\u73af\u5883\u53cb\u597d\u578b\u805a\u6c28\u916f\u50ac\u5316\u5242\u7684\u7814\u7a76\u8fdb\u5c55\u300b. \u7cbe\u7ec6\u5316\u5de5, 36(7), 1021\u20131028.\n<\/li>\n<\/ol>\n<p>\u8fd9\u4e9b\u6587\u732e\uff0c\u6709\u7684\u6765\u81ea\u56fd\u9645\u9876\u7ea7\u671f\u520a\uff0c\u6709\u7684\u51fa\u81ea\u56fd\u5185\u6838\u5fc3\u6742\u5fd7\uff0c\u5b83\u4eec\u5171\u540c\u89c1\u8bc1\u4e86DBU\u4ece\u201c\u51b7\u95e8\u8bd5\u5242\u201d\u8d70\u5411\u201c\u529f\u80fd\u660e\u661f\u201d\u7684\u5386\u7a0b\u3002\u800c\u6211\u4eec\uff0c\u6b63\u7ad9\u5728\u8fd9\u573a\u6750\u6599\u9769\u547d\u7684\u6f6e\u5934\uff0c\u770b\u7740\u4e00\u4e2a\u5c0f\u5206\u5b50\uff0c\u5982\u4f55\u64ac\u52a8\u4e00\u4e2a\u5927\u4e16\u754c\u3002<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n<ul>\n<li>\n<h3>NT CAT T-12 \u9002\u7528\u4e8e\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff0c\u5feb\u901f\u56fa\u5316\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT UL1 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6d3b\u6027\u7565\u4f4e\u4e8eT-12\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT UL22 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\uff0c\u4f18\u5f02\u7684\u8010\u6c34\u89e3\u6027\u80fd\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT UL28 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